Further searches allegedly found multiple blue satchels containing a white powder substance, which was hidden in the lining of wallets, pencil cases and laptop bags.
Presumptive testing of the powder returned a positive result for heroin, with 65kg of the product located in the luggage.
It has an estimated street value of $32 million.
They were charged with one count of importing a commercial quantity of a border-controlled drug.
They will appear at Brisbane Magistrates Court today.
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